Thirty Years with Ziegler Catalysts
نویسندگان
چکیده
منابع مشابه
The coordinative state of aluminium alkyls in Ziegler-Natta catalysts.
The most commonly used cocatalyst species in Ziegler-Natta catalysts are aluminium alkyls. In this study we aim to find the interaction between aluminium centres of these activators and other components in the ZNC system. Initially we look at binary systems of Al-alkyl/MgCl2 and ternary systems of Al-alkyl/MgCl2/TiCl4, followed by donor containing systems. The aluminium alkyls prove to be very ...
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After five decades of largely serendipitous (albeit formidable) progress, catalyst design in Ziegler-Natta olefin polymerization, i.e., the rational implementation of new active species to target predetermined polyolefin architectures, has ultimately become a realistic ambition, thanks to a much deeper fundamental understanding and major advances in the tools of computational chemistry. In this...
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Ziegler-Natta catalysis is a very important industrial process for the production of polyolefins. However, the catalysts are not well-understood at the molecular level. Yet, atomic-scale structural information is of pivotal importance for rational catalyst development. We applied a solid-state NMR/density functional theory tandem approach to gain detailed insight into the interactions between t...
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Four chromium based oxo-trinuclear carboxylate complexes were prepared by reacting chromium(III) nitrate nonahydrate with acetic acid and substituted carboxylic acids. They were characterized using infrared spectroscopy (FT-IR). Chromium content of the complexes was determined by titrimetry method. The chromium(III) monochloroacetate complex, [Cr3O(ClCH2COO)6.3H2O]NO3.3H2O in combination with d...
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ژورنال
عنوان ژورنال: Seikei-Kakou
سال: 2011
ISSN: 0915-4027,1883-7417
DOI: 10.4325/seikeikakou.23.517